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ChemicalBook > CAS DataBase List > N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos

Reaction
Product Name
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
CAS No.
1237588-12-3
Chemical Name
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
Synonyms
Mor-DalPhos;Di(1-adamantyl)-2-morpholinophenylphosphine;MorDalphos 97%;98% Mor-DalPhos;N-[2-(di-1-adamantyL;2-Morpholinophenyldi(1-adamantyl)phosphine;Bis(adamant-1-yl)(2-morpholinophenyl)phosphine;N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine;4-[2-[Di(1-Adamantyl)phosphino]phenyl]morpholine;bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane
CBNumber
CB12512504
Molecular Formula
C30H42NOP
Formula Weight
463.63
MOL File
1237588-12-3.mol
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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Property

Melting point:
219-224°C
storage temp. 
2-8°C
form 
crystal
pka
4.75±0.40(Predicted)
color 
white to yellow
Sensitive 
air sensitive
CAS DataBase Reference
1237588-12-3
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
751618
Product name
Di(1-adamantyl)-2-morpholinophenylphosphine
Purity
97%
Packaging
1g
Price
$344
Updated
2024/03/01
Sigma-Aldrich
Product number
751618
Product name
Di(1-adamantyl)-2-morpholinophenylphosphine
Purity
97%
Packaging
5g
Price
$1010
Updated
2024/03/01
Strem Chemicals
Product number
15-1092
Product name
N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos
Packaging
250mg
Price
$76
Updated
2024/03/01
Strem Chemicals
Product number
15-1092
Product name
N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos
Packaging
1g
Price
$232
Updated
2024/03/01
Sigma-Aldrich
Product number
751618
Product name
Di(1-adamantyl)-2-morpholinophenylphosphine
Purity
97%
Packaging
250mg
Price
$90.6
Updated
2024/03/01
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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Chemical Properties,Usage,Production

Reaction

  1. P-N-ligand for use in the Pd-catalyzed cross-coupling of ammonia and hydrazine. Ref. (2) with a diverse range of sterically hindered, unbiased aryl chlorides. Low catalyst loading and mild conditions. Ref (5) with diamines in a chemoselective arylation process. Ref (6) with solvent-free or aqueous conditions.
  2. P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
  3. P-N-ligand for use in the Pd-catalyzed for mono-α-arylation of ketones employing aryl chlorides, bromides, iodides, mesylates (Ref. 7) and tosylates.

Uses

Mor-DalPhos is a versatile and efficient green catalytic system for Buchwald-Hartwig cross-coupling reaction of aryl bromides or chlorides with a large set amines, amides, ureas, and carbamates.

Uses

MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Preparation Products And Raw materials

Raw materials

Preparation Products

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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Suppliers

China 80 United States 4 Global 84
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View Lastest Price from N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.
Product
N-[2-(di-1-adamantylphosphino) phenyl]morpholine 1237588-12-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
0.99
Supply Ability
500kg
Release date
2021-11-30
Career Henan Chemical Co
Product
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos 1237588-12-3
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-08

1237588-12-3, N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhosRelated Search:

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